Infrared frequency comb spectroscopy of CH2I2: Influence of hot bands and pressure broadening on the ?1 and ?6 fundamental transitions

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Infrared frequency comb spectroscopy of CH2I2: Influence of hot bands and pressure broadening on the ?1 and ?6 fundamental transitions

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  • Author: F. C. Roberts and J. H. Lehman
Direct frequency comb spectroscopy was utilized to measure the vibrational absorption spectrum of diiodomethane, CH2I2, from 2960 to 3125 cm−1. The data were obtained using a CH2I2 concentration of (6.8 ± 1.3) × 1015 molecule cm−3 and a total pressure of 10–300 mbar with either nitrogen or argon as the bath gas. The rovibrational spectra of two fundamental transitions, ν6 and ν1, were recorded and analyzed.

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